Scalable Synthesis of Bio-Based Functional Styrene: Protected Vinyl Catechol from Caffeic Acid and Controlled Radical and Anionic Polymerizations Thereof
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b04400
Abstract: Naturally abundant caffeic acid, a cinnamic acid derivative with a catechol group in its structure, was quantitatively converted into a series of protected vinyl catechol (VC) derivatives via facile and scalable decarboxylation and protection reactions.… read more here.
Keywords: caffeic acid; catechol; controlled radical; vinyl catechol ... See more keywords
Interrupted Intramolecular Hydroaminomethylation of N-Protected-2-vinyl Anilines: Novel Access to 3-Substitued Indoles or Indoline-2-ols
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27031074
Abstract: A new synthetic alternative to the synthesis of 3-methyl indoles and 3-methyl indoline-2-ols with an excellent atomic economy is presented in this study. It is demonstrated that the intramolecular interrupted hydroaminomethylation (HAM) reaction is a… read more here.
Keywords: intramolecular hydroaminomethylation; interrupted intramolecular; indoline ols; protected vinyl ... See more keywords