Extending protein-film electrochemistry across enzymology and biological inorganic chemistry to investigate, track and control the reactions of non-redox enzymes and spectroscopically silent metals
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DOI: 10.1007/s00775-025-02105-0
Abstract: Protein film electrochemistry has helped to unravel many complex reactivities of electron-transferring proteins and enzymes. A versatile descendant, the ‘Electrochemical Leaf’, offers new opportunities to extend electrochemical control to myriad enzymes that neither transfer electrons… read more here.
Keywords: chemistry; biological inorganic; electrochemistry; protein film ... See more keywords
From Protein Film Electrochemistry to Nanoconfined Enzyme Cascades and the Electrochemical Leaf
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DOI: 10.1021/acs.chemrev.2c00397
Abstract: Protein film electrochemistry (PFE) has given unrivalled insight into the properties of redox proteins and many electron-transferring enzymes, allowing investigations of otherwise ill-defined or intractable topics such as unstable Fe–S centers and the catalytic bias… read more here.
Keywords: enzyme cascades; electrochemistry; film electrochemistry; leaf ... See more keywords
Time-Independent Methodology to Access Michaelis-Menten Constant by Exploring Electrochemical-Catalytic Mechanism in Protein-Film Cyclic Staircase Voltammetry
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DOI: 10.5562/cca3383
Abstract: Protein-film voltammetry is recognized as a very efficient tool in mechanistic enzymology, but it is also seen as a relevant approach to gain thermodynamic and kinetic information related to the redox chemistry of many enzymes.… read more here.
Keywords: methodology; protein film; mechanism; electrochemical catalytic ... See more keywords