The Influence of Deuterium Isotope Effects on Structural Rearrangements, Ensemble Equilibria, and Hydrogen Bonding in Protic Ionic Liquids
Sign Up to like & getrecommendations! Published in 2022 at "Chemphyschem"
DOI: 10.1002/cphc.202200557
Abstract: Abstract We report strong isotope effects for the protic ionic liquid triethylammonium methanesulfonate [TEA][OMs] by means of deuterium solid‐state NMR spectroscopy covering broad temperature ranges from 65 K to 313 K. Both isotopically labelled PILs differ in… read more here.
Keywords: hydrogen bonding; protic ionic; deuterium; isotope effects ... See more keywords
Understanding the Role of Protic Ionic Liquids (PILs) in Reactive Systems: Rational Selection of PILs for the Design of Green Synthesis Strategies for Allylic Amines and β-Amino Esters.
Sign Up to like & getrecommendations! Published in 2019 at "ChemPlusChem"
DOI: 10.1002/cplu.201900318
Abstract: The reactive behaviour of protic ionic liquids (PILs) has been shown to be governed not only by their chemical structures but also by their global compositions, which include the presence of free acids and bases… read more here.
Keywords: protic ionic; reactive systems; amines amino; allylic amines ... See more keywords
Binary Mixtures of Aprotic and Protic Ionic Liquids Demonstrate Synergistic Polarity Effect: An Unusual Observation
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Solution Chemistry"
DOI: 10.1007/s10953-020-00952-w
Abstract: In this communication, we demonstrate the solute–solvent and solvent–solvent interactions in the binary mixtures of two aprotic ionic liquids, namely 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, with the protic ionic liquid 1-methylimidazolium acetate. The synergistic effects… read more here.
Keywords: binary mixtures; observation; protic ionic; aprotic protic ... See more keywords
Influence of Hydrogen Bonding and Ionicity of Protic Ionic Liquids on Lubricating Steel–Steel and Steel–Aluminum Contacts: Potential Ecofriendly Lubricants and Additives
Sign Up to like & getrecommendations! Published in 2020 at "Tribology Letters"
DOI: 10.1007/s11249-020-01354-1
Abstract: Three ecofriendly protic ionic liquids (PILs), 2-hydroxyethylammonium 2-ethylhexanoate, 2-hydroxymethylammonium 2-ethylhexanoate, and 2-hydroxydimethylammonium 2-ethylhexanoate, with different extents of hydrogen bonding and ionicities, were synthesized and examined as neat lubricants and lubricant additives to a mineral oil… read more here.
Keywords: steel steel; protic ionic; hydrogen bonding; aluminum ... See more keywords
Protic ionic liquid-containing silica-based ionogels for nonhumidified PEMFC applications
Sign Up to like & getrecommendations! Published in 2017 at "Ionics"
DOI: 10.1007/s11581-017-2212-9
Abstract: This paper provides details on the design of protic ionic liquids (PILs) containing silica-based ionogel for nonhumidified proton exchange membrane (PEM) applications. Specifically, we described herein a simple method of encapsulating individually four different PILs… read more here.
Keywords: containing silica; pemfc applications; silica based; protic ionic ... See more keywords
Enhanced performance for early transition metal nitrides via pseudocapacitance in protic ionic liquid electrolytes
Sign Up to like & getrecommendations! Published in 2017 at "Electrochemistry Communications"
DOI: 10.1016/j.elecom.2017.02.001
Abstract: Abstract Early transition metal nitrides achieve high capacitances via a pseudocapacitive mechanism that involves redox reactions with protons at their surfaces. Typically aqueous electrolytes are the source of protons, therefore the operating voltages are limited… read more here.
Keywords: ionic liquid; transition metal; early transition; protic ionic ... See more keywords
Critical assessment of superbase-derived protic ionic liquids as electrolytes for electrochemical applications
Sign Up to like & getrecommendations! Published in 2019 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.12.100
Abstract: Abstract Non-volatile superbased-derived protic ionic liquids are thermally stable and highly conductive, thus hold great promises for electrochemical applications. However, systematic accounts of their electrochemical properties are yet to be established. In this contribution, five… read more here.
Keywords: protic ionic; derived protic; electrochemical applications; ionic liquids ... See more keywords
Evaluation of the use of protic ionic liquids on biomass fractionation
Sign Up to like & getrecommendations! Published in 2017 at "Fuel"
DOI: 10.1016/j.fuel.2017.06.014
Abstract: Abstract This work evaluated the use of protic ionic liquids (PILs) in the pretreatment of sugarcane bagasse. Cations and anions with different chain lengths were used to synthesize four PILs, which had their performances evaluated… read more here.
Keywords: protic ionic; liquids biomass; bagasse; use protic ... See more keywords
Cryopreservation of mammalian cells using protic ionic liquid solutions.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2021.06.096
Abstract: Cryopreservation has facilitated considerable advances in both medical technology and scientific research. However, further developments have been limited by the relatively low number of effective cryoprotective agents. Even after fifty years of research, most protocols… read more here.
Keywords: cryopreservation mammalian; ionic liquid; protic ionic; mammalian cells ... See more keywords
The contrasting effects of diethylmethylamine during reduction of protons and oxidation of formic acid in diethylmethylammonium-based protic ionic liquids
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2017.10.021
Abstract: Ionic liquids are formally defined as liquids that consist entirely of ions, and which are liquid below 100 C. As these liquids are being proposed for use in a range of electrochemical devices and applications,… read more here.
Keywords: protic ionic; acid diethylmethylammonium; formic acid; diethylmethylammonium ... See more keywords
Enabling safe and stable Li metal batteries with protic ionic liquid electrolytes and high voltage cathodes
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Power Sources"
DOI: 10.1016/j.jpowsour.2020.228979
Abstract: Abstract Here, we present first examples of lithium metal cells stable and safely operating with PYRH4+(TFSI−/FSI−)-based protic ionic liquid (PIL) electrolytes, which is accomplished by encompassing vinylene carbonate (VC) in the PIL-salt solution. VC not… read more here.
Keywords: protic ionic; metal; ionic liquid; metal batteries ... See more keywords