Synthesis of Complexes with Protic NH,NR‐NHC Ligands by Oxidative Addition of N‐Alkyl‐2‐iodoimidazoles to [M(PPh3)4] (M = Pd, Pt) Complexes
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DOI: 10.1002/ejic.201700403
Abstract: The oxidative addition of N-methyl-2-iodoimidazole 1 or N-benzyl-2-iodoimidazole 2 to complexes [Pd(PPh3)4] or [Pt(PPh3)4] followed by the protonation of the unsubstituted imidazolato ring-nitrogen atom yielded complexes trans-[M(NH,NMe-NHC)(PPh3)2I] (M = Pd: trans-[3]PF6; M = Pt: trans-[4]PF6)… read more here.
Keywords: pph3; nhc pph3; trans pf6; protic nhc ... See more keywords