Aqueous-Phase Chemistry of η3-Allylpalladium(II) Complexes with Sulfonated N-Heterocyclic Carbene Ligands: Solvent Effects in the Protolysis of Pd–C Bonds and Suzuki–Miyaura Reactions
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DOI: 10.1021/acs.organomet.7b00635
Abstract: The synthesis of water-soluble η3-allyl Pd(II) complexes containing sulfonated N-heterocyclic carbene (NHC) ligands of general formula [Pd(NHC)n(η3-allyl)Cl2–n] is reported (n = 1 (1) or 2 (8)). Monocarbene complexes were obtained with the most sterically hindered… read more here.
Keywords: water; chemistry; protolysis; sulfonated heterocyclic ... See more keywords
Surface Protolysis and Its Kinetics Impact the Electrical Double Layer.
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DOI: 10.1103/physrevlett.128.056001
Abstract: Surface conductivity in the electrical double layer (EDL) is known to be affected by proton hopping and diffusion at solid-liquid interfaces. Yet, the role of surface protolysis and its kinetics on the thermodynamic and transport… read more here.
Keywords: double layer; protolysis; surface protolysis; electrical double ... See more keywords