A 4H+/4e- Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex.
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DOI: 10.1021/jacs.2c05454
Abstract: In this research article, we describe a 4H+/4e- electron-coupled-proton buffer (ECPB) based on Cu and a redox-active ligand. The protonated/reduced ECPB (complex 1: [Cu(8H+/14e-)]1+), consisting of CuI with 2 equiv of the ligand (catLH4: 1,1'-(4,5-dimethoxy-1,2-phenylene)bis(3-(tert-butyl)urea)),… read more here.
Keywords: coupled proton; electron coupled; proton buffer;