Unravelling syn- and anti- orientation in the regioselectivity of carbonyl groups of 5-fluorouracil an anticancer drug toward proton donors
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2018.09.074
Abstract: Abstract DFT and MP2 methods are used to unravel the syn and anti-configurations in the regio-stereoselectivity of carbonyl groups of 5 Fluorouracil paired with HF, CH3OH, H2O, and HCl proton donors. Two configurations of hydrogen-bonded… read more here.
Keywords: syn anti; proton donors; proton; groups fluorouracil ... See more keywords
A Mn(iv)-peroxo complex in the reactions with proton donors.
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DOI: 10.1039/c9dt00649d
Abstract: Protons play an important role in promoting O-O or M-O bond cleavage of metal-peroxo complexes. Treatment of side-on O2-bound [PPN][MnIV(TMSPS3)(O2)] (1, PPN = bis(triphenylphosphine)iminium and TMSPS3H3 = 2,2',2''-trimercapto-3,3',3''-tris(trimethylsilyl)triphenylphosphine) with perchloric acid (HClO4) in the presence… read more here.
Keywords: complex reactions; proton donors; reactions proton; peroxo complex ... See more keywords