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Published in 2017 at "Chemical record"
DOI: 10.1002/tcr.201700023
Abstract: A changeable ligand, which involves in activation of a catalyst or assists a reaction, draws an increasing attention, in contrast to a classical ligand as spectator. Proton-responsive catalysts, which are capable of undergoing changes of…
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Keywords:
catalyst;
proton responsive;
development proton;
responsive catalysts ... See more keywords
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Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06541h
Abstract: Utilizing the proton-responsive pyridinediimine ligand [(2,6-iPrC6H3)(N[double bond, length as m-dash]CMe)(N(iPr)2C2H4)(N[double bond, length as m-dash]CMe)C5H3N] (didpa), the ligand-based reduction of nitrate (NO3-) to nitric oxide (NO) was achieved. The bioinspired [Fe(Hdidpa)(CO)2]+ was shown to react with…
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Keywords:
reduction;
ligand based;
reduction nitrate;
utilizing proton ... See more keywords
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Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04253a
Abstract: The behavior of the complex (H2L)CoCl2, where H2L is a bis-(pyrazol-3-yl)pyridine, towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a dianionic pincer ligand on a d7 center. Deprotonation is…
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Keywords:
pincer;
pyrazolate;
dehydrohalogenation proton;
pincer ligand ... See more keywords
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Published in 2020 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2020.591353
Abstract: A rise in atmospheric CO2 levels, following years of burning fossil fuels, has brought about increase in global temperatures and climate change due to the greenhouse effect. As such, recent efforts in addressing this problem…
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Keywords:
metal iridium;
iridium iii;
iridium;
chiral metal ... See more keywords