Development of Proton-Responsive Catalysts.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical record"
DOI: 10.1002/tcr.201700023
Abstract: A changeable ligand, which involves in activation of a catalyst or assists a reaction, draws an increasing attention, in contrast to a classical ligand as spectator. Proton-responsive catalysts, which are capable of undergoing changes of… read more here.
Keywords: catalyst; proton responsive; development proton; responsive catalysts ... See more keywords
Ligand-based reduction of nitrate to nitric oxide utilizing a proton-responsive secondary coordination sphere.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06541h
Abstract: Utilizing the proton-responsive pyridinediimine ligand [(2,6-iPrC6H3)(N[double bond, length as m-dash]CMe)(N(iPr)2C2H4)(N[double bond, length as m-dash]CMe)C5H3N] (didpa), the ligand-based reduction of nitrate (NO3-) to nitric oxide (NO) was achieved. The bioinspired [Fe(Hdidpa)(CO)2]+ was shown to react with… read more here.
Keywords: reduction; ligand based; reduction nitrate; utilizing proton ... See more keywords
Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms.
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DOI: 10.1039/c7dt04253a
Abstract: The behavior of the complex (H2L)CoCl2, where H2L is a bis-(pyrazol-3-yl)pyridine, towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a dianionic pincer ligand on a d7 center. Deprotonation is… read more here.
Keywords: pincer; pyrazolate; dehydrohalogenation proton; pincer ligand ... See more keywords
Chiral-at-Metal: Iridium(III) Tetrazole Complexes With Proton-Responsive P-OH Groups for CO2 Hydrogenation
Sign Up to like & getrecommendations! Published in 2020 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2020.591353
Abstract: A rise in atmospheric CO2 levels, following years of burning fossil fuels, has brought about increase in global temperatures and climate change due to the greenhouse effect. As such, recent efforts in addressing this problem… read more here.
Keywords: metal iridium; iridium iii; iridium; chiral metal ... See more keywords