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Published in 2018 at "Journal of The American Society for Mass Spectrometry"
DOI: 10.1007/s13361-018-2098-4
Abstract: AbstractCollisional activation fragmentation of protonated phosphorothioates leads to skeletal rearrangement and formation of aryl sulfenylium cation (R-PhS+) via successive eliminations of CH3OH and CH3O–P=O. To better understand this unusual fragmentation reaction, isotope-labeling experiments and density…
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Keywords:
atom;
ch3oh ch3o;
phenyl ring;
protonated phosphorothioates ... See more keywords