Steric and Lewis Basicity Influence of the Second Coordination Sphere on Electrocatalytic CO2 Reduction by Manganese Bipyridyl Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02586
Abstract: This study aims to provide a greater insight into the balance between steric (bpy vs (Ph)2bpy vs mes2bpy ligands) and Lewis basic ((Ph)2bpy vs (MeOPh)2bpy vs (MeSPh)2bpy ligands) influence on the efficiencies of the protonation-first… read more here.
Keywords: ch3cn; protonation first; based precatalyst; reduction ... See more keywords