Modulation of Magnetic Anisotropy and Exchange Interaction in Phenoxide-Bridged Dinuclear Co(II) Complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00956
Abstract: We report a new class of four dimeric Co(II) complexes [Co2(bbpen)(X)2] (H2bbpen = N,N'-bis(2-hydroxybenzyl)-N,N'-bis(2-methylpyridyl)ethylenediamine) [X- = SCN (1), Cl (2), Br (3), and I (4)] with different coordination geometry of two Co(II) centers (trigonal-prismatic and… read more here.
Keywords: pseudo tetrahedral; exchange; interaction; modulation magnetic ... See more keywords
Evidence for zero-field slow magnetic relaxation in a Co(II) complex with a pseudo-tetrahedral N2I2 environment.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01336c
Abstract: Herein, we report on the synthesis, structure and magnetic properties of a four-coordinate mononuclear Co(II) diiodide complex with the 3,5-dimethylpyrazole ligand. A distorted tetrahedral local coordination environment around the central cobalt ion is formed by… read more here.
Keywords: environment; pseudo tetrahedral; relaxation; zero field ... See more keywords