Spontaneous Intercluster Electron Transfer X2- + X0 → 2 X- (X = PtAu24(SCnH2n+1)18) in Solution: Promotion by Long Alkyl Chains.
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DOI: 10.1021/jacs.2c09391
Abstract: In this work, we systematically investigated the ligand effects on spontaneous electron transfer (ET) between alkanethiolate-protected metal clusters in solution. The donor and acceptor clusters used were [PtAu24(SCnH2n+1)18]2- (8e(Cn)) and [PtAu24(SCmH2m+1)18]0 (6e(Cm)) (n, m =… read more here.
Keywords: electron transfer; alkyl chains; ptau24 scnh2n;