Syntheses, Structures, and Thermal Properties of Gyroscope-like Complexes Consisting of PtCl2 Rotators Encased in Macrocyclic Dibridgehead Diphosphines P((CH2)n)3P with Extended Methylene Chains (n = 20/22/30) and Isomers Thereof
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DOI: 10.1021/acs.organomet.8b00345
Abstract: Reactions of P((CH2)mCH═CH2)3 (2.0 equiv; m = 9 (f), 10 (g), 14 (k)) and PtCl2 in toluene give trans-PtCl2(P((CH2)mCH═CH2)3)2 (trans-1f,g,k; 63–49%). Reactions of trans-1f,g with Grubbs first generation catalyst (CH2Cl2/reflux) followed by hydrogenations (cat. PtO2)… read more here.
Keywords: ptcl2 ch2; ch2; syntheses structures; ptcl2 ... See more keywords
Photochemical H2 Evolution Catalyzed by Porphyrin-based Cubic Cages Singly and Doubly Encapsulating PtCl2(4,4′-dimethyl-2,2′-bipyridine)
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DOI: 10.1246/cl.170692
Abstract: A porphyrin-based cubic cage (Cube) was reacted with a Pt(II)-based molecular H2-evolving catalyst, PtCl2(dmbpy) (PtDmb; dmbpy: 4,4′-dimethyl-2,2′-bipyridine), to give Cubes incorporated with one o... read more here.
Keywords: ptcl2; dimethyl bipyridine; porphyrin based; based cubic ... See more keywords