Facile Styrene Formation from Ethylene and a Phenylplatinum(II) Complex Leading to an Observable Platinum(II) Hydride
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DOI: 10.1021/acs.organomet.6b00892
Abstract: A new 2-(di-tert-butylphosphanyl)benzenesulfonate-supported phenylplatinum(II) complex instantaneously but reversibly binds ethylene at room temperature. Direct and rapid styrene formation at room temperature via insertion of the PtII-bound ethylene into the PtII–Ph fragment followed by β-hydride elimination… read more here.
Keywords: styrene formation; phenylplatinum complex; ptii fragment; ptii ... See more keywords