Application of Pulse Radiolysis to Mechanistic Investigations of Catalysis Relevant to Artificial Photosynthesis.
Sign Up to like & getrecommendations! Published in 2017 at "ChemSusChem"
DOI: 10.1002/cssc.201701559
Abstract: Taking inspiration from natural photosystems, the goal of artificial photosynthesis is to harness solar energy to convert abundant materials, such as CO2 and H2 O, into solar fuels. Catalysts are required to ensure that the… read more here.
Keywords: mechanistic investigations; relevant artificial; pulse radiolysis; radiolysis ... See more keywords
Scavenging of hydrated electron by HSA or Ligand/HSA adduct: Pulse radiolysis study
Sign Up to like & getrecommendations! Published in 2018 at "Radiation Physics and Chemistry"
DOI: 10.1016/j.radphyschem.2018.07.003
Abstract: Abstract The process of electron scavenging by molecule of human serum albumin in solution under neutral pH was studied. The rate constant of reaction eaq- with HSA is diffusion controlled (1.1 × 1010 dm3 mol−1). The transient… read more here.
Keywords: hsa; pulse radiolysis; site; hydrated electron ... See more keywords
Pulse Radiolysis Studies for Mechanism in Biochemical Redox Reactions.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.8b00405
Abstract: Pulse radiolysis is a powerful method for generating highly reduced or oxidized species and free radicals. Combined with fast time-resolved spectroscopic measurement, we can monitor the reactions of intermediate species on time scales ranging from… read more here.
Keywords: radiolysis redox; pulse radiolysis; radiolysis; electron ... See more keywords
Pulse Radiolysis and Transient Absorption of Aqueous Cr(VI) Solutions up to 325 °C
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04807
Abstract: Pulse radiolysis with a custom multichannel detection system has been used to measure the kinetics of the radiation chemistry reactions of aqueous solutions of chromium(VI) to 325 °C for the first time. Kinetic traces were… read more here.
Keywords: aqueous solutions; absorption aqueous; transient absorption; radiolysis transient ... See more keywords
Coupling Pulse Radiolysis with Nanosecond Time-Resolved Step-Scan Fourier Transform Infrared Spectroscopy: Broadband Mid-Infrared Detection of Radiolytically Generated Transients
Sign Up to like & getrecommendations! Published in 2022 at "Applied Spectroscopy"
DOI: 10.1177/00037028221097429
Abstract: We describe the first implementation of broadband, nanosecond time-resolved step-scan Fourier transform infrared (S2-FT-IR) spectroscopy at a pulse radiolysis facility. This new technique allows the rapid acquisition of nano- to microsecond time-resolved infrared (TRIR) spectra… read more here.
Keywords: spectroscopy; time resolved; resolved step; pulse radiolysis ... See more keywords