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Solvent and Base in One: Tetra‐n‐butylammonium Acetate as a Multi‐Purpose Ionic Liquid Medium for Ru‐Catalyzed Directed Mono‐ and Di‐o‐C–H Arylation Reactions

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Published in 2017 at "European Journal of Organic Chemistry"

DOI: 10.1002/ejoc.201701022

Abstract: Ru-catalyzed directed o-C–H arylation reactions of 2-phenylpyridine, N-phenylpyrazole, acetophenone N-(p-methoxyphenyl)imine, and 2-phenyloxazoline proceed in good to excellent yields with a number of functionalized aryl and heteroaryl bromides in neat Bu4NOAc at 120 °C. The acetate… read more here.

Keywords: ionic liquid; purpose ionic; catalyzed directed; arylation ... See more keywords