Articles with "push pull" as a keyword



A High-Efficiency Organic Solar Cell Enabled by the Strong Intramolecular Electron Push-Pull Effect of the Nonfullerene Acceptor.

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Published in 2018 at "Advanced materials"

DOI: 10.1002/adma.201707170

Abstract: Besides broadening of the absorption spectrum, modulating molecular energy levels, and other well-studied properties, a stronger intramolecular electron push-pull effect also affords other advantages in nonfullerene acceptors. A strong push-pull effect improves the dipole moment… read more here.

Keywords: intramolecular electron; push pull; pull effect;

Electron Push‐Pull Effects for Solution and Solid‐State Emission Control in Naphthalene 2,7‐Position‐Based Donor–Acceptor–Donor

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Published in 2024 at "Asian Journal of Organic Chemistry"

DOI: 10.1002/ajoc.202400631

Abstract: Organic luminescent materials have garnered significant attention owing to their potential applications, particularly due to their inherent flexibility and ease of processability. Accordingly, the development of strategies that enable precise control over both intra‐ and… read more here.

Keywords: push pull; position based; electron push; emission ... See more keywords

Enaminone‐Based Push–Pull Chromophores: Synthesis, Optical Properties, and Computational Insights

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Published in 2025 at "Asian Journal of Organic Chemistry"

DOI: 10.1002/ajoc.202500071

Abstract: Chromophores incorporating enaminone units were efficiently synthesized using click‐type [2+2] cycloaddition‐retroelectrocyclization (CA‐RE) reactions. The preparation of electron‐rich alkynes necessary for these reactions initiated with the synthesis of alkynones via Sonogashira cross‐coupling, followed by nucleophilic conjugate… read more here.

Keywords: chromophores synthesis; based push; enaminone based; push pull ... See more keywords

Dihydropyrene as an Aromaticity Probe for Partially Quinoid Push-Pull Systems.

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Published in 2017 at "ChemPlusChem"

DOI: 10.1002/cplu.201700068

Abstract: Although aromaticity is a key concept in chemistry that is frequently used to explain the structure and reactivity of organic compounds, it remains challenging to actually measure this property. Proper probes allow for an experimental… read more here.

Keywords: aromaticity probe; aromaticity; push pull;

The Role of Planarity versus Nonplanarity in the Electronic Communication of TCAQ-Based Push-Pull Chromophores.

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Published in 2018 at "ChemPlusChem"

DOI: 10.1002/cplu.201700553

Abstract: Donor-acceptor-substituted alkynes, endowed with 11,11,12,12-tetracyano-9,10-anthraquinodimethane (TCAQ) and N,N-dimethylaniline (DMA) units, have been further functionalized by a [2+2] cycloaddition with tetracyanoethylene (TCNE) followed by a subsequent retro-electrocyclization to form distorted nonplanar structures with bridging 1,1,4,4-tetracyanobuta-1,3-diene (TCBD)… read more here.

Keywords: electronic communication; based push; tcaq based; push pull ... See more keywords

Exploring Favorable Supramolecular Interactions of Multifluorinated Aromatics in Dendronized Push-Pull Chromophores for Electro-Optics.

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Published in 2024 at "ChemPlusChem"

DOI: 10.1002/cplu.202400320

Abstract: Multifluorinated aromatics serve as supramolecular synthons in the research of organic electro-optic (EO) materials by exploiting π-π stacking interaction between the aromatic hydrocarbon and multifluorinated aromatic groups for performance improvement. However, non-classical hydrogen bonding remains… read more here.

Keywords: exploring favorable; push pull; optics; multifluorinated aromatics ... See more keywords

Synthesis and Optical Properties of Push–Push–Pull Chromophores Based on Imidazo[5,1,2‐cd]indolizines and Naphtho[1′,2′:4,5]imidazo[1,2‐a]pyridines

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Published in 2017 at "European Journal of Organic Chemistry"

DOI: 10.1002/ejoc.201701109

Abstract: Four series of new push–push–pull chromophores based on two types of heterocyclic cores, namely imidazo[5,1,2-cd]indolizines and naphtho[1′,2′:4,5]imidazo[1,2-a]pyridines, and two types of linear π spacers, namely diphenylacetylene and biphenyl, were prepared. The two isomeric heterocyclic compounds… read more here.

Keywords: pull chromophores; naphtho imidazo; push push; chromophores based ... See more keywords

Full‐color Fluorescence Solvatochromism of Push‐pull Type Indenoindene Derivatives

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Published in 2025 at "European Journal of Organic Chemistry"

DOI: 10.1002/ejoc.202401471

Abstract: Full‐color fluorescence solvatochromism was demonstrated using two carbon‐bridged oligo(phenylenevinylene) (COPV) derivatives Ph2N‐COPV1(Bu)‐COCH3 and [Ph2N‐COPV1(Bu)]2CO with a push–pull system, where the donor and acceptor moieties are diphenylamino and a carbonyl group, respectively. In non‐polar cyclohexane, the… read more here.

Keywords: push pull; full color; fluorescence solvatochromism; color fluorescence ... See more keywords

Evaluating a push-pull strategy for management of Drosophila suzukii Matsumura in red raspberry.

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Published in 2018 at "Pest management science"

DOI: 10.1002/ps.4666

Abstract: BACKGROUND Drosophila suzukii Matsumura is a serious pest of small fruits that lays its eggs in growing fruit. Current management strategies rely on an unsustainable schedule of foliar applications of chemical insecticides. Alternative approaches to… read more here.

Keywords: pull; oviposition; suzukii; management ... See more keywords

A push-pull strategy for controlling the tea green leafhopper (Empoasca flavescens F.) using semiochemicals from Tagetes erecta and Flemingia macrophylla.

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Published in 2022 at "Pest management science"

DOI: 10.1002/ps.6840

Abstract: The tea green leafhopper, Empoasca flavescens is the most important pest in Chinese tea plantations. For decades its control has been executed almost exclusively through pesticide applications. A semiochemical-based ‘push-pull’ strategy was tested on the… read more here.

Keywords: push pull; pull strategy; pull; tea ... See more keywords

Modelling push-pull management of pest insects using repellents and attractive traps in fruit tree orchards.

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Published in 2022 at "Pest management science"

DOI: 10.1002/ps.7005

Abstract: BACKGROUND Push-pull with semiochemicals in pest management uses repellents to reduce response of pests to food-mate resources (push) and attractive traps to reduce populations (pull). Simulation models of push-pull can aid understanding of plant-insect interactions… read more here.

Keywords: push pull; insects; management; attractive traps ... See more keywords