Assembling the Puzzle of Coparsite Polymorphism: Synthesis, Thermal Expansion, and Quantum Magnetism of α- and β-Cu4O2(VO4)Cl.
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DOI: 10.1021/acs.inorgchem.4c03694
Abstract: Two new dimorphic spin-1/2 quantum magnets, α- and β-Cu4O2(VO4)Cl, were synthesized via a chemical vapor transport method that emulates mineral formation in volcanic fumaroles. α-Cu4O2(VO4)Cl (1) is a pure vanadate analogue of the coparsite mineral… read more here.
Keywords: assembling puzzle; coparsite polymorphism; cu4o2 vo4; puzzle coparsite ... See more keywords