Two isolated Zn-ε-Keggin decorated by pyridine-imidazole with excellent electrocatalytic and third-order NLO properties
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119169
Abstract: Abstract Based on {e-PMoV8MoVI4O40Zn4} POM units, two novel organic–inorganic hybrids, [TBA]2[H3PMoV8MoVI4O40Zn4]2[4-pyim]6·7H2O (1) (4-pyim = 4-(imidazol-2-yl)pyridine) and [H3PMoV8MoVI4O40Zn4][2-pyim]4·3H2O (2) (2-pyim = 2-(imidazol-2-yl)pyridine), have been triumphantly gained under the hydrothermal conditions via self-assembly method. Compound 1 is made up of two… read more here.
Keywords: nlo properties; third order; properties two; pyim ... See more keywords
Dual-nodes bridged cobalt-modified Keggin-type polyoxometalate-based chains for highly efficient CO2 photoconversion.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt01757a
Abstract: The design of efficient catalysts for photocatalytic CO2 conversion is of great importance for the sustainable development of society. Herein, three polyoxometalate (POM)-based crystalline materials were formulated prepared by substituting transition metals and adjusting solvent… read more here.
Keywords: siw12o40 pyim; pyim; dual nodes; co2 ... See more keywords