Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis.
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DOI: 10.1021/jacs.9b01352
Abstract: A new class of chiral iron catalysts is introduced that contains exclusively achiral ligands with the overall chirality being the result of a stereogenic iron center. Specifically, iron(II) is cis-coordinated to two N-(2-pyridyl)-substituted N-heterocyclic carbene… read more here.
Keywords: iron; pynhc ligands; chiral iron; metal catalysis ... See more keywords