Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-Oxo Intermediate.
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DOI: 10.1021/jacs.7b11400
Abstract: The reaction of [(PyNMe3)FeII(CF3SO3)2], 1, with excess peracetic acid at -40 °C generates a highly reactive intermediate, 2b(PAA), that has the fastest rate to date for oxidizing cyclohexane by a nonheme iron species. It exhibits… read more here.
Keywords: meo pynme3; highly reactive; spectroscopic dft; fev ... See more keywords