Metal–Dithiolene Bonding Contributions to Pyranopterin Molybdenum Enzyme Reactivity
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DOI: 10.3390/inorganics8030019
Abstract: Here we highlight past work on metal-dithiolene interactions and how the unique electronic structure of the metal-dithiolene unit contributes to both the oxidative and reductive half reactions in pyranopterin molybdenum and tungsten enzymes. The metallodithiolene… read more here.
Keywords: pyranopterin molybdenum; metal dithiolene; reactivity; molybdenum ... See more keywords