Pyranoside‐into‐Furanoside Rearrangement of 4‐Pentenyl Glycosides in the Synthesis of a Tetrasaccharide‐Related to Galactan I of Klebsiella pneumoniae
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DOI: 10.1002/ejoc.201601413
Abstract: An efficient strategy for synthesis of spacer-armed tetrasaccharide related to galactan I of Klebsiella pneumoniae was reported employing newly developed acid-free conditions for pyranoside-into-furanoside (PIF) rearrangement of a digalactoside bearing 4-pentenyl group at anomeric position.… read more here.
Keywords: galactan klebsiella; related galactan; klebsiella pneumoniae; tetrasaccharide related ... See more keywords
Driving Force of the Pyranoside-into-Furanoside Rearrangement
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DOI: 10.1021/acsomega.8b03274
Abstract: Ab initio calculations of fully O-sulfated model monosaccharides, including common hexoses (glucose, galactose, fucose, and mannose) and pentoses (arabinose and xylose), were performed to study the energetic properties of the recently discovered pyranoside-into-furanoside (PIF) rearrangement.… read more here.
Keywords: force pyranoside; rearrangement; pyranoside furanoside; pif rearrangement ... See more keywords