Synthesis and Structure of Alkaline Earth Bis{hydrido-tris(3,5-diisopropyl-pyrazol-1-yl)borate} Complexes: Ae(TpiPr2)2 (Ae = Mg, Ca, Sr, Ba).
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DOI: 10.1021/acs.inorgchem.0c03294
Abstract: The synthesis and structural characterization of Ae(TpiPr2)2 (Ae = Mg, Ca, Sr, Ba; TpiPr2 = hydrido-tris(3,5-diisopropyl-pyrazol-1-yl)borate) are reported. In the crystalline state, the alkaline earth metal centers are six-coordinate, even the small Mg2+ ion, with… read more here.
Keywords: hydrido tris; tpipr2; diisopropyl pyrazol; pyrazol borate ... See more keywords
Exploring opportunities for tuning phenyltris(pyrazol-1-yl)borate donation by varying the extent of phenyl substituent fluorination.
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DOI: 10.1039/d3dt00735a
Abstract: The importance of electron deficient Tp ligands motivates the introduction of electron-withdrawing substituents into the scorpionate framework. Since perfluorophenyltris(pyrazol-1-yl)borate affects significant anodic shifts in half-cell potentials in their metal complexes relative those of phenyltris(pyrazol-1-yl)borate analogues,… read more here.
Keywords: pyrazol borate; phenyl; phenyltris pyrazol; metal ... See more keywords