Supramolecular Interaction Tuning of Spin-Crossover in Pyrene/Fullerene (C60 ) Tethered FeII -2,6-Di(pyrazol-1-yl)pyridine Complexes: Towards Switchable Molecular Devices
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201801109
Abstract: A set of functional SCO systems based on FeII-2,6di(pyrazol-1-yl)pyridine (BPP), FeII-BPP, featuring supramolecular pyrene and fullerene (C60) anchoring groups for nanocarbon materials are designed and synthesized. The pyrene tethered complexes [Fe(L)2](BF4)2 and [Fe(L)2](BF4)2 comprise structurally… read more here.
Keywords: pyrene; pyrene fullerene; fullerene c60; pyrazol pyridine ... See more keywords
Spin-Crossover in Supramolecular Iron(II)–2,6-bis(1H-Pyrazol-1-yl)pyridine Complexes: Toward Spin-State Switchable Single-Molecule Junctions
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c07217
Abstract: Spin-crossover (SCO) active iron(II) complexes are an integral class of switchable and bistable molecular materials. Spin-state switching properties of the SCO complexes have been studied in the bulk and single-molecule levels to progress toward fabricating… read more here.
Keywords: single molecule; state; spin state; pyrazol pyridine ... See more keywords
Synthesis and electronic investigation of mono- and di-substituted 4-nitro- and 4-amino-pyrazol-1-yl bis(pyrazol-1-yl)pyridine-type ligands and luminescent Eu(iii) derivatives.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01153a
Abstract: Four new disubstituted and monosubstituted nitro- and amino- bis(pyrazol-1-yl)pyridine (bppy) ligands, substituted at the pyrazole 4-position (1, 2, 5, 6) have been synthesized, along with two luminescent Eu(iii) tris-β-diketonate derivatives of the amino substituted ligands… read more here.
Keywords: pyrazol; pyrazol pyridine; nitro amino; luminescent iii ... See more keywords
Iron(II) complex of 2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid (ppCOOH) suitable for surface deposition
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1430790
Abstract: Abstract The synthesis, structural and magnetic characterization of the tris iron(II) complex of 2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid (ppCOOH) ligand are reported in [Fe(ppCOOH)3](ClO4)2·0.5H2O·2EtOH. Single crystal structure and magnetic characterization of the bulk compound show that the low-spin… read more here.
Keywords: iron complex; pyrazol pyridine; pyridine carboxylic; carboxylic acid ... See more keywords