Trinuclear copper(II) pyrazolate compounds: a long story of serendipitous discoveries and rational design
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DOI: 10.1039/c7ce00009j
Abstract: In the past decade great effort has been put into the development of synthetic strategies to produce trinuclear triangular CuII (TTC) arrays, which may be synthetic analogues of the trinuclear site in ascorbate oxidase and… read more here.
Keywords: pyrazolate; compounds long; long story; trinuclear copper ... See more keywords
Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms.
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DOI: 10.1039/c7dt04253a
Abstract: The behavior of the complex (H2L)CoCl2, where H2L is a bis-(pyrazol-3-yl)pyridine, towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a dianionic pincer ligand on a d7 center. Deprotonation is… read more here.
Keywords: pincer; pyrazolate; dehydrohalogenation proton; pincer ligand ... See more keywords
Relativistic modulation of supramolecular halogen/copper interactions and phosphorescence in Cu(I) pyrazolate cyclotrimers.
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DOI: 10.1039/d2dt03725d
Abstract: Described herein are the synthesis, structure, and photophysics of the iodo-substituted cyclic trinuclear copper(I) complex, Cu3[4-I-3,5-(CF3)2Pz]3 supported by a highly-fluorinated pyrazolate in comparison with its previously reported 4-Br/4-Cl analogues. The crystal structure is stabilised by… read more here.
Keywords: modulation supramolecular; copper; relativistic modulation; pyrazolate ... See more keywords