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   Articles with "pyrazolate" as a keyword



Conversion of Metal Pyrazolate/(Hydr)oxide Clusters into Nanojars: Solution vs Solid-State Structure and Magnetism

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recommendations! Published in 2024 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.4c01698

Abstract: Nanojars are a class of anion binding and extraction agents composed of a series of [Cu(μ-OH)(μ-pz)]n (pz = pyrazolate; n = 26–36) supramolecular metal–organic complexes. In contrast to other anion binding agents amenable to liquid–liquid… read more here.

Keywords: hydr oxide; pyrazolate; pyrazolate hydr; metal ... See more keywords

Stable Microporous Metal-Organic Framework Based on Tritopic Pyrazolate Ligand for Xe/Kr Separation.

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recommendations! Published in 2024 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.4c04646

Abstract: Pyrazolate ligands, renowned for their potent electron-donating capabilities, have emerged as promising building blocks for the construction of stable metal-organic frameworks (MOFs) particularly when paired with late transition metals. While a plethora of diverse MOFs… read more here.

Keywords: pyrazolate; separation; framework; ligand ... See more keywords
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Trinuclear copper(II) pyrazolate compounds: a long story of serendipitous discoveries and rational design

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recommendations! Published in 2017 at "CrystEngComm"

DOI: 10.1039/c7ce00009j

Abstract: In the past decade great effort has been put into the development of synthetic strategies to produce trinuclear triangular CuII (TTC) arrays, which may be synthetic analogues of the trinuclear site in ascorbate oxidase and… read more here.

Keywords: pyrazolate; compounds long; long story; trinuclear copper ... See more keywords

Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms.

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recommendations! Published in 2018 at "Dalton transactions"

DOI: 10.1039/c7dt04253a

Abstract: The behavior of the complex (H2L)CoCl2, where H2L is a bis-(pyrazol-3-yl)pyridine, towards Brønsted bases is studied, to evaluate peripheral NH deprotonation as a route to a dianionic pincer ligand on a d7 center. Deprotonation is… read more here.

Keywords: pincer; pyrazolate; dehydrohalogenation proton; pincer ligand ... See more keywords

Relativistic modulation of supramolecular halogen/copper interactions and phosphorescence in Cu(I) pyrazolate cyclotrimers.

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recommendations! Published in 2023 at "Dalton transactions"

DOI: 10.1039/d2dt03725d

Abstract: Described herein are the synthesis, structure, and photophysics of the iodo-substituted cyclic trinuclear copper(I) complex, Cu3[4-I-3,5-(CF3)2Pz]3 supported by a highly-fluorinated pyrazolate in comparison with its previously reported 4-Br/4-Cl analogues. The crystal structure is stabilised by… read more here.

Keywords: modulation supramolecular; copper; relativistic modulation; pyrazolate ... See more keywords