Functional Pyrimidinyl Pyrazolate Pt(II) Complexes: Role of Nitrogen Atom in Tuning the Solid‐State Stacking and Photophysics
Sign Up to like & getrecommendations! Published in 2019 at "Advanced Functional Materials"
DOI: 10.1002/adfm.201900923
Abstract: Pt(II) metal complexes are known to exhibit strong solid‐state aggregation and are promising for realization of efficient emission in fabrication of organic light emitting diodes (OLED) with nondoped emitter layer. Four pyrimidine–pyrazolate based chelates, together… read more here.
Keywords: pyrazolate complexes; solid state; pyrimidinyl pyrazolate; functional pyrimidinyl ... See more keywords
Multinuclear magnetic resonance studies of five silver(I) trinuclear pyrazolate complexes
Sign Up to like & getrecommendations! Published in 2020 at "Structural Chemistry"
DOI: 10.1007/s11224-020-01661-2
Abstract: Experimental multinuclear determination of the chemical shifts, especially 15 N and 109 Ag, of five silver(I) trinuclear pyrazolate complexes, (PzAg) 3 , coupled with ZORA (zeroth-order regular approximation) and GIAO (gauge-independent atomic orbital) calculations, has… read more here.
Keywords: silver trinuclear; trinuclear pyrazolate; five silver; pyrazolate complexes ... See more keywords
Formation of Excimers in Isoquinolinyl Pyrazolate Pt(II) Complexes: Role of Cooperativity Effects.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02780
Abstract: The interplay between noncovalent interactions involving metal complexes may lead to the formation of aggregates (i.e., ground state dimers, trimers, n-mers, etc.), and this is often linked to dramatic changes in their physical and chemical… read more here.
Keywords: cooperativity effects; isoquinolinyl pyrazolate; formation; pyrazolate complexes ... See more keywords
Nitrite Reduction by Trinuclear Copper Pyrazolate Complexes: An Example of a Catalytic, Synthetic Polynuclear NO Releasing System.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00748
Abstract: Two trinuclear CuII pyrazolato complexes with a Cu3(μ3-E)-core (E = O2- or OH-) and terminal nitrite ligands in two coordination modes were characterized crystallographically, spectroscopically, and electrochemically. One-electron oxidation of the μ3-O species produces a… read more here.
Keywords: reduction; reduction trinuclear; trinuclear copper; pyrazolate complexes ... See more keywords