Expanding the Family of Pyrazole-Bridged Mixed-Spin and Mixed-Valence Tetranuclear [2 × 2] Iron Grid Complexes
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DOI: 10.1002/ejic.201700733
Abstract: The new bis(tridentate) compartmental proligand 3,5-bis(6-(1-methyl-1H-imidazole-2-yl)pyrid-2-yl)pyrazole (HLim) was synthesized and used for the self-assembly of a rugged tetranuclear [2 × 2] Fe4 grid complex [FeII4Lim4](ClO4)4 (1), which readily forms upon reaction of HLim with Fe(ClO4)2‧6H2O… read more here.
Keywords: spin; pyrazole bridged; clo4; grid ... See more keywords
Theoretical study of magnetic interaction in pyrazole-bridged dinuclear Cu(II) complex
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.03.017
Abstract: Abstract A difference in a magnetic behavior of two different types of pyrazole-bridged dinuclear Cu(II) complexes are explained by a concept of the orbital complementarity and the density functional theory (DFT) calculations. The DFT calculations… read more here.
Keywords: theoretical study; study magnetic; magnetic interaction; pyrazole bridged ... See more keywords