Electrochemical and Kinetic Insights into Molecular Water Oxidation Catalysts Derived from Cp*Ir(pyridine‐alkoxide) Complexes
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DOI: 10.1002/cctc.201800916
Abstract: We report the solution‐phase electrochemistry of seven half‐sandwich iridium(III) complexes with varying pyridine‐alkoxide ligands to quantify electronic ligand effects that translate to their activity in catalytic water oxidation. Our results unify some previously reported electrochemical… read more here.
Keywords: water; pyridine alkoxide; water oxidation; kinetic insights ... See more keywords
Ligand Tuning in Pyridine-Alkoxide Ligated Cp*IrIII Oxidation Catalysts
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DOI: 10.1021/acs.organomet.7b00492
Abstract: Six novel derivatives of pyridine-alkoxide ligated Cp*IrIII complexes, potent precursors for homogeneous water and C–H oxidation catalysts, have been synthesized, characterized, and analyzed spectroscopically and kinetically for ligand effects. Variation of alkoxide and pyridine substituents… read more here.
Keywords: oxidation catalysts; alkoxide ligated; oxidation; pyridine alkoxide ... See more keywords