Synthesis and Characterization of Pyridine Dipyrrolide Uranyl Complexes
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DOI: 10.1021/acs.inorgchem.2c00348
Abstract: The first actinide complexes of the pyridine dipyrrolide (PDP) ligand class, (MesPDPPh)UO2(THF) and (Cl2PhPDPPh)UO2(THF), are reported as the UVI uranyl adducts of the bulky aryl substituted pincers (MesPDPPh)2– and (Cl2PhPDPPh)2– (derived from 2,6-bis(5-(2,4,6-trimethylphenyl)-3-phenyl-1H-pyrrol-2-yl)pyridine (H2MesPDPPh, Mes… read more here.
Keywords: thf; pyridine dipyrrolide; pyridine; uo2 thf ... See more keywords
Bismuth Pyridine Dipyrrolide Complexes: a Transient Bi(II) Species Which Ring Opens Cyclic Ethers.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02314
Abstract: A family of group 15 MIII pyridine dipyrrolide complexes has been prepared and fully characterized; the reduction of these complexes was investigated with traditional strong metal reductants, which led either to over-reduction in the case… read more here.
Keywords: transient species; bismuth pyridine; pyridine dipyrrolide; complexes transient ... See more keywords