Bis-Ferrocenyl-Pyridinediimine Trinuclear Mixed-Valent Complexes with Metal-Binding Dependent Electronic Coupling: Synthesis, Structures, and Redox-Spectroscopic Characterization.
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DOI: 10.1021/jacs.0c10015
Abstract: A family of metal dichloride complexes having a bis-ferrocenyl-substituted pyridinediimine ligand was systematically synthesized ((Fc2PDI)MCl2, M = Mg, Zn, Fe, and Co) and characterized crystallographically, spectroscopically, electrochemically, and computationally. Electronic coupling between the ligand ferrocene… read more here.
Keywords: electronic coupling; metal; bis ferrocenyl; pyridinediimine ... See more keywords