A General Synthetic Strategy toward Highly Doped Pyridinic Nitrogen‐Rich Carbons
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DOI: 10.1002/adfm.202006076
Abstract: Doping carbon materials with p‐block elements such as nitrogen is an effective approach to tune electronic properties of the framework and can endow the host's new characters. To date, highly doped carbons with tunable nitrogen… read more here.
Keywords: nitrogen; nitrogen rich; strategy; doped pyridinic ... See more keywords
Grain Boundary Perfection Enabled by Pyridinic Nitrogen Doped Graphdiyne in Hybrid Perovskite
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DOI: 10.1002/adfm.202104633
Abstract: The solution processing in hybrid perovskite films inevitably results in the formation of detrimental defects at grain boundaries (GBs) that deteriorate the optoelectronic properties and bring about severe hysteresis as well as operational instability. Here,… read more here.
Keywords: hybrid perovskite; nitrogen doped; pyridinic nitrogen; doped graphdiyne ... See more keywords
Pyridinic Nitrogen Sites Dominated Coordinative Engineering of Subnanometric Pd Clusters for Efficient Alkynes’ Semihydrogenation
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DOI: 10.1002/adma.202209635
Abstract: Supported metal catalysts have played an important role in optimizing selective semihydrogenation of alkynes for fine chemicals. There into, nitrogen‐doped carbons, as a type of promising support materials, have attracted extensive attentions. However, due to… read more here.
Keywords: alkynes semihydrogenation; pyridinic nitrogen; subnanometric clusters; nitrogen sites ... See more keywords
Pyridinic Nitrogen Modification for Selective Acetylenic Homocoupling on Au(111).
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DOI: 10.1021/jacs.2c11799
Abstract: On-surface acetylenic homocoupling has been proposed to construct carbon nanostructures featuring sp hybridization. However, the efficiency of linear acetylenic coupling is far from satisfactory, often resulting in undesired enyne products or cyclotrimerization products due to… read more here.
Keywords: modification selective; acetylenic homocoupling; pyridinic nitrogen; nitrogen modification ... See more keywords
Pyridinic nitrogen dominated doping on Pd/carbon catalysts for enhanced hydrogenation performance
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.1046058
Abstract: The hydrogenation of 4-carboxylbenzaldehyde over Pd catalysts is a crucial process during the production of pure terephthalic acid. Herein, ZIF-8 derived carbon materials (NC) with adjustable N types were synthesized and used as the supports… read more here.
Keywords: nitrogen dominated; carbon; hydrogenation; pyridinic nitrogen ... See more keywords