Mononuclear Rhodium(II) and Iridium(II) Complexes Supported by Tetradentate Pyridinophane Ligands.
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DOI: 10.1021/acs.inorgchem.7b01619
Abstract: The tetradentate ligands N,N'-dialkyl-2,11-diaza[3,3](2,6)pyridinophane (RN4, where R = Me or tBu) were employed to synthesize and fully characterize [(RN4)MI(COD)]+ complexes (M = Rh or Ir; COD = cyclooctadiene). Interestingly, these complexes exhibit accessible oxidation potentials… read more here.
Keywords: mononuclear rhodium; rhodium; pyridinophane; rhodium iridium ... See more keywords