Ligand Effects and Kinetic Investigations of Sterically Accessible 2-Pyridonate Tantalum Complexes for Hydroaminoalkylation
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.7b01486
Abstract: The synthesis of a series of structurally varied pyridonate-supported tantalum amido complexes and their catalytic reactivity in the intermolecular α-alkylation of unprotected secondary amines are described. Both terminal and internal alkenes can undergo this hydroaminoalkylation… read more here.
Keywords: tantalum; pyridonate; ligand effects; pyridonate tantalum ... See more keywords
Vanadium pyridonates: dimerization, redox behaviour, and metal-ligand cooperativity.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02177c
Abstract: The synthesis, structure, and reactivity of vanadium pyridonate complexes are described. Vanadium(III) pyridonate complexes were accessed through protonolysis and reduction of a tetrakis(amido)vanadium(IV) starting material. Bis(pyridonate) vanadium(IV) precursors could be isolated depending on the amount… read more here.
Keywords: vanadium; pyridonate; pyridonates dimerization; dimerization redox ... See more keywords