Nature-Inspired Radical Pyridoxal-Mediated C-C Bond Formation.
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DOI: 10.1021/jacs.4c05997
Abstract: Pyridoxal-5'-phosphate (PLP) and derivatives of this cofactor enable a plethora of reactions in both enzyme-mediated and free-in-solution transformations. With few exceptions in each category, such chemistry has predominantly involved two-electron processes. This sometimes poses a… read more here.
Keywords: pyridoxal; inspired radical; nature inspired; radical pyridoxal ... See more keywords