A highly stable and luminescent mononuclear Cu(I) bis-{5-tert-butyl-3-(6-methyl-2-pyridyl)-1H-1,2,4-triazole} complex
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DOI: 10.1016/j.cclet.2016.12.015
Abstract: Abstract A new emissive mononuclear homoleptic Cu(I) complex of 5-tert-butyl-3-(6-methyl-2-pyridyl)-1H-1,2,4-triazole (bmptzH), [Cu(bmptzH)2](ClO4) (1), has been synthesized by treatment of [Cu(PPh3)2(CH3CN)2](ClO4) or [Cu(CH3CN)4](ClO4) with the bmptzH ligand. It is revealed that complex 1 displays a distorted… read more here.
Keywords: methyl; pyridyl triazole; methyl pyridyl; tert butyl ... See more keywords
Two new mononuclear zinc(II) and cadmium(II) coordination polymers based on 4-(3-pyridyl)-2H-1,2,3-triazole: Syntheses, structures, theoretical and fluorescent properties
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DOI: 10.1016/j.poly.2019.03.028
Abstract: Abstract Two new d10 metal coordination polymers (CPs), [Zn(L)NO3]n (1) and [Cd(L)I2]n (2) (L = 4-(3-Pyridyl)-2H-1,2,3-triazole), have been designed and synthesized from ZnII/CdII ions and the rigid L ligand. The CPs 1 and 2 have been structurally… read more here.
Keywords: two new; new mononuclear; coordination polymers; mononuclear zinc ... See more keywords
Novel polyoxometalate-based cobalt complexes based on rigid pyridyl-triazole-tetrazole and pyridyl-bis(triazole) ligands
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DOI: 10.1039/c8ce01158c
Abstract: Three novel polyoxometalate (POM)-based metal–organic complexes (MOCs) constructed from rigid pyridyl-triazole-tetrazole and pyridyl-bis(triazole) ligands have been hydrothermally synthesized and structurally characterized: [Co3(Htyptz)2(γ-Mo8O26)(H2O)6]·4H2O (1), H2[Co3(Htyptz)2(TeMo6O24)(H2O)8]·6H2O (2), [Co3(Hpyttz)2(γ-Mo8O26)(H2O)8]·2H2O (3) (H2typtz = 3-(tetrazol-5-yl)-5-(pyrid-3-yl)-1,2,4-triazolyl, H2pyttz = 3-(pyrid-4-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl). Single-crystal X-ray… read more here.
Keywords: rigid pyridyl; pyridyl triazole; mo8o26; metal organic ... See more keywords
Coligand effects on the architectures and magnetic properties of octahedral cobalt(ii) complexes with easy-axis magnetic anisotropy
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DOI: 10.1039/c9ce01871a
Abstract: Two mononuclear azido–cobalt(II) complexes, with the formulas [Co(3,3-Hbpt)2(N3)2(H2O)2] (1) and [Co(abpt)2(N3)2]·H2O (2) (3,3-Hbpt = 1H-3,5-bis(3-pyridyl)-1,2,4-triazole; abpt = 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole), have been prepared by altering the pyridyl-triazole coligands. In both complexes, the Co(II) centers feature hexa-coordinated environments… read more here.
Keywords: coligand effects; pyridyl triazole; cobalt complexes; axis magnetic ... See more keywords