Pincer Platinum(II) Hydrides: High Stability Imparted by Donor-Flexible Pyridylidene Amide Ligands and Evidence for Adduct Formation before Protonation.
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DOI: 10.1021/acs.inorgchem.2c04363
Abstract: Donor-flexible ligands are an emerging class of noninnocent ligands. Their ability to adapt their donating strength toward a metal center has had numerous catalytic advantages yet has never been utilized to stabilize and isolate intermediate… read more here.
Keywords: flexible pyridylidene; protonation; pyridylidene amide; donor flexible ... See more keywords
Pyridylidene Amide Ru Complex for Selective Oxidation in Organic Synthesis.
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DOI: 10.1021/acs.orglett.2c00177
Abstract: The ruthenium(II) bis(PYA) complex 1 (PYA = p-pyridylidene amide) is a powerful catalyst for the oxidation of sulfides to sulfones, of alkenes to carbonyl compounds, and of terminal alkynes to carboxylic acids by using NaIO4… read more here.
Keywords: amide complex; oxidation; oxidation organic; pyridylidene amide ... See more keywords