From Pincer to Paddlewheel: C-H and C-S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II).
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DOI: 10.1021/acs.inorgchem.8b03568
Abstract: The bis(2-pyridylthio)methanidopalladium(II) pincer complex (1), containing a Pd-C bond, was obtained from the reaction of bis(2-pyridylthio)methane (H2L) with palladium(II) acetate in toluene under reflux. When palladium(II) trifluoroacetate was used, H2L reacted to generate the tetrakis(pyridine-2-thiol)palladium(II)… read more here.
Keywords: pincer; palladium; pyridylthio methane; bis pyridylthio ... See more keywords