Chlorogenation of pyrrole-based on di(pyridyl)pyrrolide ligand and synthesis of its ruthenium carbonyl complexes
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.04.046
Abstract: Abstract The treatment of 2-(5-(pyridin-2-yl)-1H-pyrrol-2-yl)pyridine (HL1) and PhICl2 as halogenation reagent generated monochloro-pyrrole HL2, dichloro-pyrrole HL3 and penta-chloro L4. The reaction of HL3 with [Ru(CO)2Cl2]n gave diruthenium(I) complex [Ru2(μ-κ2N,N′:κ1N″-L3)2(CO)4] (1) and monoruthenium(II) complex [Ru(κ3N,N′,N‴-L3)(κ2N,N′-L3)(CO)] (2).… read more here.
Keywords: pyrrole; pyrrole based; chlorogenation pyrrole; ruthenium ... See more keywords
Novel activated N-doped hollow microporous carbon nanospheres from pyrrole-based hyper-crosslinking polystyrene for supercapacitors
Sign Up to like & getrecommendations! Published in 2019 at "Reactive and Functional Polymers"
DOI: 10.1016/j.reactfunctpolym.2019.104326
Abstract: Abstract Here, pyrrole-based hollow microporous organic nanospheres (Py-HMONs) were firstly synthesized through co-hyper-cross-linking of pyrrole and polylactide-b-polystyrene (PLA-b-PS) diblock copolymers based on Scholl reaction. The effect of diblock copolymers and pyrrole amount on the morphology… read more here.
Keywords: pyrrole based; carbon nanospheres; doped hollow; hollow microporous ... See more keywords
Pyrrolo[3,2-b]pyrrole-Based Quinoidal Compounds For High Performance n-Channel Organic Field-Effect Transistor
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.8b01791
Abstract: It is a very important and challenging topic to design high performance n-channel organic semiconductors with a new type conjugated skeleton. Herein, a new class of n-channel organic semiconductors, pyrrolo[3,2-b]pyrrole-based quinoidal molecules QBPBP and QFBPBP,… read more here.
Keywords: performance channel; channel organic; channel; pyrrolo pyrrole ... See more keywords
Electropolymerization of Pyrrole-Based Ionic Liquids on Selected Wireless Bipolar Electrodes.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c25230
Abstract: This paper describes an electropolymerization-based on-chip valving system, accomplished by electrosynthesis of conductive polymeric ionic liquid (CPIL) films at selected points within an array of bipolar electrodes (BPEs), in which each of these wireless electrodes… read more here.
Keywords: polymer; cpil; bipolar electrodes; polymer film ... See more keywords
Calix[4]pyrrole-Based Azo-Bridged Porous Organic Polymer for Bromine Capture.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08327
Abstract: The toxicity, corrosiveness, and volatility of elemental bromine presents challenges for its safe storage and transportation. Purification from other halogens is also difficult. Here, we report an easy-to-prepare calix[4]pyrrole-based azo-bridged porous organic polymer (C4P-POP) that… read more here.
Keywords: calix pyrrole; azo bridged; bromine; capture ... See more keywords
Synthesis of pyrrole-based PSiP pincer ligands and their palladium, rhodium, and platinum complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00948j
Abstract: The synthesis and coordination chemistry of a new class of silyl pincer ligand featuring pyrrole-based linkers is reported. The steric and electronic properties of these bis(phosphinopyrrole)methylsilane ligands were interrogated using their palladium, rhodium, and platinum… read more here.
Keywords: platinum complexes; pincer; palladium rhodium; rhodium platinum ... See more keywords
Iron pyrrole-based PNP pincer ligand complexes as catalyst precursors.
Sign Up to like & getrecommendations! Published in 2017 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229617009287
Abstract: The structure of a pincer ligand consists of a backbone and two `arms' which typically contain a P or N atom. They are tridentate ligands that coordinate to a metal center in a meridional configuration.… read more here.
Keywords: based pnp; iron; pyrrole based; pincer ligand ... See more keywords
A Concise Synthesis of Pyrrole-Based Drug Candidates from α-Hydroxyketones, 3-Oxobutanenitrile, and Anilines
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031265
Abstract: A simple and concise three-component synthesis of a key pyrrole framework was developed from the reaction between α-hydroxyketones, oxoacetonitriles, and anilines. The synthesis was used to obtain several pyrrole-based drug candidates, including COX-2 selective NSAID,… read more here.
Keywords: based drug; drug candidates; synthesis; pyrrole based ... See more keywords