Synthesis, structure and electrochemistry properties of [Ru2(CO)4]2+ complexes with di(pyridyl)pyrrolide ligands
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.05.027
Abstract: Abstract Treatment of [Ru 3 (CO) 12 ] with 2,5-di(2-pyridyl)pyrrole (HL1) and 2,5-di(2-(5-bromopyridyl)pyrrole (HL2) in refluxing toluene afforded the dinuclear Ru(I) carbonyl complexes [Ru 2 (CO) 4 (L)] (L = L1 ( 1 ), L2 ( 3… read more here.
Keywords: electrochemistry properties; pyrrolide ligands; electrochemistry; synthesis structure ... See more keywords
Long-lived photoluminescence from an eight-coordinate zirconium(IV) complex with four 2-(2'-pyridyl)pyrrolide ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04912k
Abstract: The photoluminescent eight-coordinate zirconium complex Zr(HPMPH)4 supported by four monoanionic 2-(2'-pyridine)pyrrolide ligands was synthesized. This molecule shows dual emission via fluorescence and phosphorescence with an overall quantum efficiency of 4% at room temperature in solution.… read more here.
Keywords: pyrrolide ligands; eight coordinate; zirconium complex; coordinate zirconium ... See more keywords