Surface-bound quadruple H-bonded dimers: formation and exchange kinetics.
Sign Up to like & getrecommendations! Published in 2017 at "Faraday discussions"
DOI: 10.1039/c7fd00068e
Abstract: While the mechanistic details of the dimerization of the self-complementary 2-ureido-4(1H)-pyrimidinone (UPy) motif are well studied in solution, no such investigation is available on a surface. Here we report an extensive study of hydrogen binding… read more here.
Keywords: surface bound; bonded dimers; quadruple bonded; exchange ... See more keywords
Crystal structure of a trifluoromethyl benzoato quadruple-bonded dimolybdenum complex
Sign Up to like & getrecommendations! Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s205698902200010x
Abstract: The quadruple-bond complex, [Mo2(p-O2CC6H4CF3)4ยท2THF], crystallizes in the triclinic space group P with intercalated pentane/THF lattice solvent molecules. The electron-withdrawing group on the paddlewheel carboxylate together with the axial THF molecules lead to a slight lengthening… read more here.
Keywords: structure trifluoromethyl; trifluoromethyl benzoato; crystal structure; quadruple bonded ... See more keywords