Quadruple bonding of bare group-13 atoms in transition metal complexes.
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DOI: 10.1039/d0dt02773a
Abstract: Density functional theory calculations at the M06-D3/def2-TZVPPD level of the group-13 anion complexes EFe(CO)3- (E = B-Tl) and the isoelectronic neutral and charged boron adducts BTM(CO)3q (TMq = Fe-, Ru-, Os-, Co, Rh, Ir, Ni+,… read more here.
Keywords: group atoms; quadruple bonding; group; transition metal ... See more keywords