Cyclocarbopalladation/Stille Cascade: Stereoselective Access to Quaternary Functionalized Carbons.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02400
Abstract: Exploration of the 4-exo-dig cyclocarbopalladation in the discovery of new and original scaffolds afforded some unexpected results. The search for a way to produce seven-membered ring systems led to polycyclic molecules bearing a tetrasubstituted carbon.… read more here.
Keywords: cyclocarbopalladation stille; stille cascade; access quaternary; stereoselective access ... See more keywords
Quaternary functionalized mesoporous adsorbents for ultra-high kinetics of CO2 capture from air
Sign Up to like & getrecommendations! Published in 2020 at "Scientific Reports"
DOI: 10.1038/s41598-020-77477-1
Abstract: Obstacles to widespread deployments of direct air capture of CO2 (DAC) lie in high material and energy costs. By grafting quaternary ammonium (QA) functional group to mesoporous polymers with high surface area, a unique DAC… read more here.
Keywords: high kinetics; adsorption; ultra high; air ... See more keywords