Enantioselective construction of quaternary tetrahydropyridines by palladium-catalyzed vinylborylation of alkenes.
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DOI: 10.1039/c7cc01488k
Abstract: Here, the highly enantioselective construction of 3,3-disubstituted tetrahydropyridines via Pd(0)-catalyzed asymmetric vinylborylation of (Z)-1-iodo-dienes and B2pin2 in the presence of a (S)-p-CF3-BnPHOX ligand is reported. This process is supposed to be initiated by oxidative addition… read more here.
Keywords: tetrahydropyridines palladium; construction; enantioselective construction; construction quaternary ... See more keywords