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Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04151g
Abstract: Four copper(II)-flavonolate compounds of type [Cu(LR)(fla)] {where LR = 2-(p-R-benzyl(dipyridin-2-ylmethyl)amino)acetate; R = -OMe (1), -H (2), -Cl (3) and -NO2 (4)} have been developed as a structural and functional enzyme-substrate (ES) model of the Cu2+-containing…
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Keywords:
fla;
flavonolate;
copper;
quercetin dioxygenase ... See more keywords
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1
Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02853k
Abstract: This paper demonstrates the metal ion effects on the quercetin 2,4-dioxygenase (2,4-QD)-like reactivity. For this purpose, a series of five metal(II)-acetato complexes [MII(L)(OAc)] {M = Mn (1OAc), Co (2OAc), Ni (3OAc), Cu (4OAc), Zn (5OAc);…
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Keywords:
quercetin dioxygenase;
effects metal;
metal cofactors;
reactivity ... See more keywords