A Computational Mechanistic Study of Metal‐Catalyzed Remote C–H Functionalizations – Insights into the Origin of Regioselectivity and the Role of Acid
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201601111
Abstract: The metal-catalyzed remote C–H functionalization of quinoline N-oxide was investigated systematically through density functional theory calculations. We found that the coordination of the N-oxide moiety to a metal center greatly lowered the barrier to C–H… read more here.
Keywords: quinoline oxide; catalyzed remote; metal; role ... See more keywords
Cp*Co(III)-Catalyzed C(8)-Nucleophilic Cascade Cyclization of Quinoline N-Oxide with 1,6-Enyne.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00305
Abstract: The C(8)-selective nucleophilic cascade cyclization of quinoline N-oxide with easily derived 1,6-enyne from phenol derivatives is demonstrated. A variety of quinoline N-oxide and alkynes are discovered to be suitable for producing a library of quinoline… read more here.
Keywords: quinoline oxide; cascade cyclization; cyclization quinoline; nucleophilic cascade ... See more keywords
Crystal structures of three zinc(II) halide coordination complexes with quinoline N-oxide
Sign Up to like & getrecommendations! Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989022005953
Abstract: The structures of the three related compounds dichloridobis(quinoline N-oxide-κO)zinc(II); dibromidobis(quinoline N-oxide-κO)zinc(II) and diiodidobis(quinoline N-oxide-κO)zinc(II) are presented. read more here.
Keywords: zinc; structures three; three zinc; crystal structures ... See more keywords