Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00197
Abstract: Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products and is compatible… read more here.
Keywords: allyl; hiyama cross; highly enantioselective; enantioselective hiyama ... See more keywords
Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides
Sign Up to like & getrecommendations! Published in 2019 at "Nature Protocols"
DOI: 10.1038/s41596-019-0209-8
Abstract: Although Csp 2–Csp 2 Suzuki–Miyaura couplings (SMCs) are widely used in small-molecule synthesis, related methods that allow the incorporation of Csp 3-hybridized coupling partners, particularly in an asymmetric manner, are less developed. This protocol describes… read more here.
Keywords: enantioselective rhodium; rhodium; rhodium catalyzed; highly enantioselective ... See more keywords