Photoinduced, Copper-Catalyzed Enantioconvergent Alkylations of Anilines by Racemic Tertiary Electrophiles: Synthesis and Mechanism.
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DOI: 10.1021/jacs.1c12749
Abstract: Transition-metal catalysis of substitution reactions of alkyl electrophiles by nitrogen nucleophiles is beginning to emerge as a powerful strategy for synthesizing higher-order amines, as well as controlling their stereochemistry. Herein, we report that a readily… read more here.
Keywords: copper; racemic tertiary; mechanism; catalyzed enantioconvergent ... See more keywords