Stereodivergent Pd/Cu Catalysis for the Dynamic Kinetic Asymmetric Transformation of Racemic Unsymmetrical 1,3-Disubstituted Allyl Acetates.
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DOI: 10.1021/jacs.0c02150
Abstract: A stereodivergent Pd/Cu catalyst system has been developed for the unprecedented dynamic kinetic asymmetric transformation (DyKAT) of racemic unsymmetrical 1,3-disubstituted allylic acetates with prochiral aldimine esters. A series of α,α-disubstituted α-amino acids bearing vicinal stereocenters… read more here.
Keywords: unsymmetrical disubstituted; racemic unsymmetrical; asymmetric transformation; kinetic asymmetric ... See more keywords