Racemization of Secondary‐Amine‐Containing Natural Products Using Heterogeneous Metal Catalysts
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DOI: 10.1002/cctc.201800293
Abstract: Heterogeneously catalyzed racemization reactions of the secondary amines (S)‐1‐methyl‐6,7‐dimethoxy‐1,2,3,4‐tetrahydroisoquinoline (salsolidine) and (S)‐1‐methyl‐1,2,3,4‐tetrahydro‐ß‐carboline were investigated using Pd, Pt, and Ir on carbon or Al2O3 supports. A comparison of kinetics and deactivation on selected platinum and iridium… read more here.
Keywords: platinum; natural products; containing natural; amine containing ... See more keywords